The Organometallic Chemistry of the Transition MetalsJohn Wiley & Sons, 28 de mar. de 2014 - 528 páginas Fully updated and expanded to reflect recent advances, the sixth edition of this bestselling text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features:
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Conteúdo
| ii | |
| vii | |
2 Types of Ligand | xlix |
Making Sense of Organometallic Complexes | xliii |
1 FirstRow Carbonyls | xlv |
Alkylsand Hydrides | 3 |
4 d 8 Metals that Can Adopt a 16e Square | 6 |
Problems | 6-1 |
Oxidative Addition and Reductive Elimination | 6-4 |
1 Common Oxidative Additions by d | 6-6 |
Fragmentation | 6-27 |
References | 6-28 |
and Hydroboration | 7-9 |
Clusters Nanoparticles Materials and Surfaces | 7-13 |
References | 7-29 |
6 Relationships between Oxidation States | 12 |
7 Common Geometries with Their Typical d | 19 |
9 Pauling Electronegativities of the Transition | 27 |
References | 3-38 |
10 Effect of Changing Metal NetIonic Charge | 3-43 |
PiComplexes | 5-13 |
DewarChatt versus Metalacyclopropane | 5-15 |
between Metals | 5-37 |
References | 5-48 |
Addition and Abstraction | 7-34 |
References | 21 |
Paramagnetic and High OxidationState Complexes | 9-15 |
Physical Methods | 9-37 |
Note | 9-74 |
Bonds | 9-106 |
Bioorganometallic Chemistry | 9-193 |
| 41 | |
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Termos e frases comuns
18e complex abstraction acceptor acid agostic alkane alkene alkyl alkyne allyl anion atoms back bonding back donation binding C–H bond carbonyl catalyst charge Chem cluster compounds configuration coordination number coupling covalent cyclometalation dissociation donor electron count electronegative electrophilic ethylene example favored Figure Fischer Fischer carbenes fragment geometry give halide homogeneous homogeneous catalysts hydride hydrogenation intermediate inthe ionic isomers kinetic ligand lone pairs M–M bond mechanism metal complexes metallocene metathesis methyl migratory insertion molecule nucleophilic attack octahedral ofthe orbitals organometallic chemistry oxidative addition pathway Pd(II phosphines polar polymer protons R. H. Crabtree radical reaction reactivity reacts reagent reductive elimination resonance reverse Schrock Section shown shows solvent species spectroscopy spectrum square planar stable stereochemistry steric structure substitution substrate themetal thermodynamically togive tothe trans trans effect transition metals typically undergo