The Organometallic Chemistry of the Transition Metals

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John Wiley & Sons, 28 de mar de 2014 - 528 páginas
Fully updated and expanded to reflect recent advances, the sixth edition of this bestselling text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry.

This edition features:

  • New sections on Multifunctional Ligands, Oxidation Catalysis, and Green Chemistry
  • Expanded discussion on topics from the fifth edition: Supramolecular Chemistry, N-Heterocyclic Carbenes, Coupling Reactions, Organometallic Materials, Applications to Organic Synthesis, and Bioorganometallic Chemistry
  • End-of-chapter problems and their solutions
 

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Conteúdo

Title page
List of Tables
ii
Periodic Tableofthe
vii
2 Types of Ligand
xlix
Making Sense of Organometallic Complexes
xliii
1 FirstRow Carbonyls
xlv
Alkylsand Hydrides
3
4 d 8 Metals that Can Adopt a 16e Square
6
Problems
6-1
Oxidative Addition and Reductive Elimination
6-4
1 Common Oxidative Additions by d
6-6
Fragmentation
6-27
References
6-28
and Hydroboration
7-9
Clusters Nanoparticles Materials and Surfaces
7-13
References
7-29

6 Relationships between Oxidation States
12
7 Common Geometries with Their Typical d
19
9 Pauling Electronegativities of the Transition
27
References
3-38
10 Effect of Changing Metal NetIonic Charge
3-43
PiComplexes
5-13
DewarChatt versus Metalacyclopropane
5-15
between Metals
5-37
References
5-48
Addition and Abstraction
7-34
References
21
Paramagnetic and High OxidationState Complexes
9-15
Physical Methods
9-37
Note
9-74
Bonds
9-106
Bioorganometallic Chemistry
9-193
Useful Texts on Allied Topics
41

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Sobre o autor (2014)

Robert H. Crabtree, Ph. D., is Whitehead professor in the Department of Chemistry at Yale University. He has served on the editorial boards of Chemical Reviews, New Journal of Chemistry, Journal of Molecular Catalysis, and Organometallics and has received numerous awards for his research accomplishments including the Centenary Prize of the Royal Society of Chemistry (2014) and the Organometallic Chemistry Prize of the American Chemical Society (1993).

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