Modern Molecular PhotochemistryBenjamin/Cummings Publishing Company, 1978 - 628 páginas Inleiding tot de studie van organische fotochemische reacties |
De dentro do livro
Resultados 1-3 de 75
Página 59
... vibrational motion is obtained in Figure 4.4 from the intersection of the potential - energy curve with the correspond- ing energy level . The classical turning points are the positions which define the potential energy - i.e . , at the ...
... vibrational motion is obtained in Figure 4.4 from the intersection of the potential - energy curve with the correspond- ing energy level . The classical turning points are the positions which define the potential energy - i.e . , at the ...
Página 102
... vibrational pattern that is characteristic of the C = O vibrational stretch in So ( see Fig . 5.13 ) .16 Such a vibrational pattern is expected for emission from a n , * state if the transition is localized on the C = O group , i.e. ...
... vibrational pattern that is characteristic of the C = O vibrational stretch in So ( see Fig . 5.13 ) .16 Such a vibrational pattern is expected for emission from a n , * state if the transition is localized on the C = O group , i.e. ...
Página 174
... vibrational levels of S1 . From Figure 6.13 it can be seen that if the vibrational eigenfunctions for XS , ( a high - energy vibrational level of So ) oscillates from negative to positive values rapidly in the region where 7S ...
... vibrational levels of S1 . From Figure 6.13 it can be seen that if the vibrational eigenfunctions for XS , ( a high - energy vibrational level of So ) oscillates from negative to positive values rapidly in the region where 7S ...
Conteúdo
1 | 10 |
Electronic Orbitals Configurations and States | 17 |
7 | 21 |
Direitos autorais | |
33 outras seções não mostradas
Outras edições - Ver todos
Termos e frases comuns
absorption acceptor acetone aromatic benzene benzophenone bimolecular bond carbonyl Chem chemical CIDNP collision compounds configuration conrotatory correlation diagram corresponds cyclic cycloaddition Dewar benzene dipole diradical donor efficiency electrocyclic electrocyclic reactions electron spin electronically excited emission energy transfer ethylene example excimer exciplex experimental Figure fluid solution fluorescence formation Franck-Condon hydrogen abstraction intermediate internal conversion intersystem crossing intramolecular jump k₁ kcal/mole ketones lifetime magnetic field mechanism molecular molecule naphthalene nuclear geometry nuclear motion observed occur organic molecules oscillator oxetane oxygen pathway Ph Ph phosphorescence photochemical photochemistry photocycloaddition photon Photophysics photoreactions photosensitized Phys possess processes quantum yield quencher quenching radiationless transitions radiative radical pair rate constant reactant reaction reactive rearrangement representative point result ring S₁ S₁(n S₂ sec¯¹ sec¹ sensitization singlet solvent spectroscopic spectrum spin-orbit coupling structure symmetry T₁ temperature triplet triplet-triplet Turro undergo vibrational x-cleavage Zero Order zwitterionic