Modern Molecular PhotochemistryBenjamin/Cummings Publishing Company, 1978 - 628 páginas Inleiding tot de studie van organische fotochemische reacties |
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Página 91
... SPECTRUM b MOLECULE SUB STATES WITH DISTINCT SPECTRUM WITH VIBRATIONAL STRUCTURE Absorption Emission Absorption Emission MOLECULE WITH MANY UNRESOLVED SUBSTATES Absorption Emission In Absorption Emission BROAD BAND SPECTRUM Figure 5.6 ...
... SPECTRUM b MOLECULE SUB STATES WITH DISTINCT SPECTRUM WITH VIBRATIONAL STRUCTURE Absorption Emission Absorption Emission MOLECULE WITH MANY UNRESOLVED SUBSTATES Absorption Emission In Absorption Emission BROAD BAND SPECTRUM Figure 5.6 ...
Página 140
... spectrum of either component would be identical to that of each monomer , i.e. , neither component would influence the other . As D and A approach , the absorption spectrum remains constant . Even- tually , D and A undergo collisions ...
... spectrum of either component would be identical to that of each monomer , i.e. , neither component would influence the other . As D and A approach , the absorption spectrum remains constant . Even- tually , D and A undergo collisions ...
Página 617
... spectrum , 127 phosphorescence excitation spectrum , 127 photoreduction to benzpin- acol , 262 state - energy diagram , 179 transitions , 106 , 107 Benzophenone - coumarin sys- tem state - energy dia- gram , 463 1 - benzoyl - 4- ( a ...
... spectrum , 127 phosphorescence excitation spectrum , 127 photoreduction to benzpin- acol , 262 state - energy diagram , 179 transitions , 106 , 107 Benzophenone - coumarin sys- tem state - energy dia- gram , 463 1 - benzoyl - 4- ( a ...
Conteúdo
1 | 10 |
Electronic Orbitals Configurations and States | 17 |
7 | 21 |
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absorption acceptor acetone aromatic benzene benzophenone bimolecular bond carbonyl Chem chemical CIDNP collision compounds configuration conrotatory correlation diagram corresponds cyclic cycloaddition Dewar benzene dipole diradical donor efficiency electrocyclic electrocyclic reactions electron spin electronically excited emission energy transfer ethylene example excimer exciplex experimental Figure fluid solution fluorescence formation Franck-Condon hydrogen abstraction intermediate internal conversion intersystem crossing intramolecular jump k₁ kcal/mole ketones lifetime magnetic field mechanism molecular molecule naphthalene nuclear geometry nuclear motion observed occur organic molecules oscillator oxetane oxygen pathway Ph Ph phosphorescence photochemical photochemistry photocycloaddition photon Photophysics photoreactions photosensitized Phys possess processes quantum yield quencher quenching radiationless transitions radiative radical pair rate constant reactant reaction reactive rearrangement representative point result ring S₁ S₁(n S₂ sec¯¹ sec¹ sensitization singlet solvent spectroscopic spectrum spin-orbit coupling structure symmetry T₁ temperature triplet triplet-triplet Turro undergo vibrational x-cleavage Zero Order zwitterionic