Modern Molecular PhotochemistryBenjamin/Cummings Publishing Company, 1978 - 628 páginas Inleiding tot de studie van organische fotochemische reacties |
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... orbital . The node of the newly generated p orbital is parallel to the propagation vector of the light wave . The p orbital may be viewed as a wave form which vibrates up and down through a plane containing the nucleus - i.e . , an ...
... orbital . The node of the newly generated p orbital is parallel to the propagation vector of the light wave . The p orbital may be viewed as a wave form which vibrates up and down through a plane containing the nucleus - i.e . , an ...
Página 206
... orbital interactions with n Figure 7.4 Orbital interactions of the n , * state with substrates . d π ( 0 ) state nucleophilic orbital interactions with π * with one lobe of the no orbital . This interaction should be important whenever ...
... orbital interactions with n Figure 7.4 Orbital interactions of the n , * state with substrates . d π ( 0 ) state nucleophilic orbital interactions with π * with one lobe of the no orbital . This interaction should be important whenever ...
Página 207
... orbital electron occupations , we can immediately deduce the state symmetries . The protocol for classification of ... Orbital symmetry Φί a a S S SASAS State symmetry ij Φ.Φ ; S AAS H مد Molecular plane n - orbital " in - plane ...
... orbital electron occupations , we can immediately deduce the state symmetries . The protocol for classification of ... Orbital symmetry Φί a a S S SASAS State symmetry ij Φ.Φ ; S AAS H مد Molecular plane n - orbital " in - plane ...
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Electronic Orbitals Configurations and States | 17 |
7 | 21 |
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absorption acceptor acetone aromatic benzene benzophenone bimolecular bond carbonyl Chem chemical CIDNP collision compounds configuration conrotatory correlation diagram corresponds cyclic cycloaddition Dewar benzene dipole diradical donor efficiency electrocyclic electrocyclic reactions electron spin electronically excited emission energy transfer ethylene example excimer exciplex experimental Figure fluid solution fluorescence formation Franck-Condon hydrogen abstraction intermediate internal conversion intersystem crossing intramolecular jump k₁ kcal/mole ketones lifetime magnetic field mechanism molecular molecule naphthalene nuclear geometry nuclear motion observed occur organic molecules oscillator oxetane oxygen pathway Ph Ph phosphorescence photochemical photochemistry photocycloaddition photon Photophysics photoreactions photosensitized Phys possess processes quantum yield quencher quenching radiationless transitions radiative radical pair rate constant reactant reaction reactive rearrangement representative point result ring S₁ S₁(n S₂ sec¯¹ sec¹ sensitization singlet solvent spectroscopic spectrum spin-orbit coupling structure symmetry T₁ temperature triplet triplet-triplet Turro undergo vibrational x-cleavage Zero Order zwitterionic