Modern Molecular PhotochemistryBenjamin/Cummings Publishing Company, 1978 - 628 páginas Inleiding tot de studie van organische fotochemische reacties |
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Página 18
... function for nuclear position and motion and let represent the approximate wave function for spin direction and motion , then Y " true " molecular wave function Ψο χ S ↑ 1 ( 2.1 ) orbital nuclear spin approximate wave functions A ...
... function for nuclear position and motion and let represent the approximate wave function for spin direction and motion , then Y " true " molecular wave function Ψο χ S ↑ 1 ( 2.1 ) orbital nuclear spin approximate wave functions A ...
Página 19
... function of a molecule , Y , was defined in terms of a solution of a wave equation . The spirit of the meaning of the " true molecular wave function " is similar to the spirit of the conservation laws , which we assume to be correct in ...
... function of a molecule , Y , was defined in terms of a solution of a wave equation . The spirit of the meaning of the " true molecular wave function " is similar to the spirit of the conservation laws , which we assume to be correct in ...
Página 218
... function for the 2 configuration ( Fig . 7.11b ) at the planar geometry is essentially covalent in character , i.e. , there is very little ionic character to planar ethylene , and the wave function for 2 has ( in terms of atomic ...
... function for the 2 configuration ( Fig . 7.11b ) at the planar geometry is essentially covalent in character , i.e. , there is very little ionic character to planar ethylene , and the wave function for 2 has ( in terms of atomic ...
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1 | 10 |
Electronic Orbitals Configurations and States | 17 |
7 | 21 |
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absorption acceptor acetone aromatic benzene benzophenone bimolecular bond carbonyl Chem chemical CIDNP collision compounds configuration conrotatory correlation diagram corresponds cyclic cycloaddition Dewar benzene dipole diradical donor efficiency electrocyclic electrocyclic reactions electron spin electronically excited emission energy transfer ethylene example excimer exciplex experimental Figure fluid solution fluorescence formation Franck-Condon hydrogen abstraction intermediate internal conversion intersystem crossing intramolecular jump k₁ kcal/mole ketones lifetime magnetic field mechanism molecular molecule naphthalene nuclear geometry nuclear motion observed occur organic molecules oscillator oxetane oxygen pathway Ph Ph phosphorescence photochemical photochemistry photocycloaddition photon Photophysics photoreactions photosensitized Phys possess processes quantum yield quencher quenching radiationless transitions radiative radical pair rate constant reactant reaction reactive rearrangement representative point result ring S₁ S₁(n S₂ sec¯¹ sec¹ sensitization singlet solvent spectroscopic spectrum spin-orbit coupling structure symmetry T₁ temperature triplet triplet-triplet Turro undergo vibrational x-cleavage Zero Order zwitterionic