Modern Molecular PhotochemistryBenjamin/Cummings Publishing Company, 1978 - 628 páginas Inleiding tot de studie van organische fotochemische reacties |
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Página 36
... diagram of a typical chromophore is of enormous importance in under- standing of photoreactions . What is a state diagram and what information does it provide the photochemist ? The state diagram relates the energies of the lowest ...
... diagram of a typical chromophore is of enormous importance in under- standing of photoreactions . What is a state diagram and what information does it provide the photochemist ? The state diagram relates the energies of the lowest ...
Página 208
... diagram . The state correlation diagram is then generated by connecting the states of reactants to the states of the primary product . This First Order state correlation diagram is considered to be a working set of surfaces , which ...
... diagram . The state correlation diagram is then generated by connecting the states of reactants to the states of the primary product . This First Order state correlation diagram is considered to be a working set of surfaces , which ...
Página 209
... diagram . All curve crossings of states of the same symmetry are replaced by avoidings . The resulting diagram is a First Order adiabatic state correlation diagram . With the First Order state correlation diagram in hand we have a means ...
... diagram . All curve crossings of states of the same symmetry are replaced by avoidings . The resulting diagram is a First Order adiabatic state correlation diagram . With the First Order state correlation diagram in hand we have a means ...
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1 | 10 |
Electronic Orbitals Configurations and States | 17 |
7 | 21 |
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absorption acceptor acetone aromatic benzene benzophenone bimolecular bond carbonyl Chem chemical CIDNP collision compounds configuration conrotatory correlation diagram corresponds cyclic cycloaddition Dewar benzene dipole diradical donor efficiency electrocyclic electrocyclic reactions electron spin electronically excited emission energy transfer ethylene example excimer exciplex experimental Figure fluid solution fluorescence formation Franck-Condon hydrogen abstraction intermediate internal conversion intersystem crossing intramolecular jump k₁ kcal/mole ketones lifetime magnetic field mechanism molecular molecule naphthalene nuclear geometry nuclear motion observed occur organic molecules oscillator oxetane oxygen pathway Ph Ph phosphorescence photochemical photochemistry photocycloaddition photon Photophysics photoreactions photosensitized Phys possess processes quantum yield quencher quenching radiationless transitions radiative radical pair rate constant reactant reaction reactive rearrangement representative point result ring S₁ S₁(n S₂ sec¯¹ sec¹ sensitization singlet solvent spectroscopic spectrum spin-orbit coupling structure symmetry T₁ temperature triplet triplet-triplet Turro undergo vibrational x-cleavage Zero Order zwitterionic