Modern Molecular PhotochemistryUniversity Science Books, 1991 - 628 páginas During the last two decades the photochemistry of organic molecules has grown into an important and pervasive branch of organic chemistry. In Modern Molecular Photochemistry, the author brings students up to date with the advances in this field - the development of the theory of photoreactions, the utilization of photoreactions in synthetic sequences, and the advancement of powerful laser techniques to study the mechanisms of photoreactions. |
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... Fluorescence and Phosphorescence 146 5.14 Emission from " Upper " Excited Singlets and Triplets ; The Azulene Anomaly 148 References 148 6 Photophysical Radiationless Transitions 153 6.1 Photophysical Radiationless Transitions as a Form ...
... Fluorescence and Phosphorescence 146 5.14 Emission from " Upper " Excited Singlets and Triplets ; The Azulene Anomaly 148 References 148 6 Photophysical Radiationless Transitions 153 6.1 Photophysical Radiationless Transitions as a Form ...
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Conteúdo
2 | 8 |
1 | 9 |
Electronic Orbitals Configurations and States | 17 |
2 | 21 |
9 | 28 |
11 | 36 |
5 | 43 |
4 | 52 |
63 | 144 |
72 | 150 |
Photophysical Radiationless Transitions | 153 |
69 | 174 |
74 | 179 |
8 | 180 |
Theoretical Organic Photochemistry | 199 |
Mechanistic Organic Photochemistry | 232 |
6 | 64 |
8 | 70 |
Emission of Light | 76 |
5 | 91 |
7 | 103 |
9 | 112 |
11 | 132 |
56 | 137 |
13 | 143 |
Energy Transfer | 296 |
Photoaddition and Photosubstitution Reactions | 362 |
Cycloaddition Reactions | 414 |
Isomerizations and Rearrangements | 473 |
Photofragmentation Reactions | 526 |
Singlet Oxygen and Chemiluminescent | 579 |
Epilogue | 615 |
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Termos e frases comuns
absorption abstraction acceptor addition allowed aromatic atom benzene bond Chem chemical compounds configuration consider correlation corresponds coupling depends diagram diradical direct donor effect efficiency electron emission emission spectrum energy transfer ethylene example exciplex excited expected experimental factors field Figure fluorescence formation function geometry given ground hydrogen important initial interaction intermediate intersystem crossing involved jump kcal/mole ketones Letters lifetime light magnetic magnitude measured mechanism mixing molecular molecule motion nuclear observed occur orbital organic oscillator pair pathway phosphorescence photochemical photoreactions Phys possess possible probability processes pure quantum quantum mechanical quenching radiative radical rate constant reaction reactive Reference relative representative result ring rule S₁ sensitizer separation singlet solvent species spectrum spin spin-orbit structure surface symmetry T₁ Table temperature triplet Type undergo vibrational wave yield Zero Order