Modern Molecular PhotochemistryDuring the last two decades the photochemistry of organic molecules has grown into an important and pervasive branch of organic chemistry. In Modern Molecular Photochemistry, the author brings students up to date with the advances in this field - the development of the theory of photoreactions, the utilization of photoreactions in synthetic sequences, and the advancement of powerful laser techniques to study the mechanisms of photoreactions. |
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Conteúdo
Preface | 12 |
Potential Energy Surfaces | 12 |
Electronic Orbitals Configurations and States | 17 |
Emission of Light | 76 |
Photophysical Radiationless Transitions | 153 |
Theoretical Organic Photochemistry | 199 |
Diagrams for a Selected Reaction Coordinate | 207 |
Mechanistic Organic Photochemistry | 232 |
Photoaddition and Photosubstitution Reactions | 362 |
Reactions | 368 |
Cycloaddition Reactions | 414 |
Isomerizations and Rearrangements | 473 |
Photofragmentation Reactions | 526 |
Singlet Oxygen and Chemiluminescent | 579 |
Photoreactions | 608 |
Energy Transfer | 296 |
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Termos e frases comuns
absorption acceptor addition allowed atom benzene bond Chem chemical complex compounds configuration consider correlation corresponds coupling depends derived diagram diradical direct discussed donor effect efficiency electron emission emission spectrum energy transfer ethylene example exciplex excited expected experimental factors favored field Figure fluorescence formation function geometry given ground hydrogen abstraction important initial interaction intermediate intersystem crossing involved jump kcal/mole ketones Letters lifetime light magnetic measured mechanism molecular molecule motion nuclear observed occur orbital organic oscillator pair pathway phosphorescence photochemical photochemistry photoreactions Phys possess possible probability processes quantum quantum mechanical quenching radiationless radiative radical rate constant reaction reactive rearrangement references relative representative result ring rule sensitizer separation singlet solvent species spectrum spin structure surface symmetry Table temperature transition triplet Type undergo vibrational wave yield Zero Order