Modern Molecular PhotochemistryUniversity Science Books, 1991 - 628 páginas During the last two decades the photochemistry of organic molecules has grown into an important and pervasive branch of organic chemistry. In Modern Molecular Photochemistry, the author brings students up to date with the advances in this field - the development of the theory of photoreactions, the utilization of photoreactions in synthetic sequences, and the advancement of powerful laser techniques to study the mechanisms of photoreactions. |
Conteúdo
2 | 8 |
1 | 9 |
Electronic Orbitals Configurations and States | 17 |
2 | 21 |
9 | 28 |
11 | 36 |
5 | 43 |
4 | 52 |
63 | 144 |
72 | 150 |
Photophysical Radiationless Transitions | 153 |
69 | 174 |
74 | 179 |
8 | 180 |
Theoretical Organic Photochemistry | 199 |
Mechanistic Organic Photochemistry | 232 |
6 | 64 |
8 | 70 |
Emission of Light | 76 |
5 | 91 |
7 | 103 |
9 | 112 |
11 | 132 |
56 | 137 |
13 | 143 |
Energy Transfer | 296 |
Photoaddition and Photosubstitution Reactions | 362 |
Cycloaddition Reactions | 414 |
Isomerizations and Rearrangements | 473 |
Photofragmentation Reactions | 526 |
Singlet Oxygen and Chemiluminescent | 579 |
Epilogue | 615 |
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Termos e frases comuns
a-cleavage acceptor acetone aromatic benzene benzophenone bond carbonyl Chem chemical CIDNP collision compounds correlation diagram corresponds cyclic cycloaddition Dewar benzene dipole diradical donor efficiency electrocyclic electrocyclic reactions electron spin electronically excited energy transfer ethylene example excimer exciplex experimental Figure fluid solution fluorescence formation Franck-Condon heavy atom hydrocarbons hydrogen abstraction ibid interaction intermediate internal conversion intersystem crossing intramolecular isomerization jump k₁ kcal/mole ketones lifetime light magnetic field mechanism molecular molecule naphthalene nuclear geometry observed occur organic molecules oscillator oxetane oxygen pathway Ph Ph phosphorescence photochemical photochemistry photon photophysical photoreactions photosensitized Phys possess processes quantum yield quencher quenching radiationless transitions radical pair rate constant reactant reaction reactive rearrangement representative point result S₁ S₁(n S₂ sec¯¹ sec¹ sensitizer singlet solvent spectroscopic spin-orbit coupling structure surface symmetry T₁ T₂ temperature triplet triplet-triplet Turro undergo vector vibrational wave Zero Order zwitterionic