Modern Molecular PhotochemistryUniversity Science Books, 1991 - 628 páginas During the last two decades the photochemistry of organic molecules has grown into an important and pervasive branch of organic chemistry. In Modern Molecular Photochemistry, the author brings students up to date with the advances in this field - the development of the theory of photoreactions, the utilization of photoreactions in synthetic sequences, and the advancement of powerful laser techniques to study the mechanisms of photoreactions. |
Conteúdo
Organic PhotochemistryAn Overview | 1 |
Electronic Orbitals Configurations and States | 17 |
Transitions Between StatesChemical Dynamics | 38 |
Potential Energy Surfaces | 52 |
Radiative TransitionsThe Absorption | 76 |
Photophysical Radiationless Transitions | 153 |
Theoretical Organic Photochemistry | 199 |
Mechanistic Organic Photochemistry | 232 |
Energy Transfer | 296 |
Photoaddition and Photosubstitution Reactions | 362 |
Cycloaddition Reactions | 414 |
Isomerizations and Rearrangements | 473 |
Photofragmentation Reactions | 526 |
Singlet Oxygen and Chemiluminescent | 579 |
Epilogue | 615 |
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Termos e frases comuns
a-cleavage absorption acceptor acetone aromatic atom benzene benzophenone bimolecular bond carbonyl CH3 CH3 Chem chemical chemiluminescent CIDNP cis-trans isomerization cleavage collision compounds configuration conrotatory correlation diagram corresponds cyclic cycloaddition Dewar benzene dipole diradical donor efficiency electrocyclic electrocyclic reactions electron spin electronically excited emission energy transfer enones ethylene example exciplex experimental Figure fluorescence formation Franck-Condon hydrogen abstraction ibid intermediate internal conversion intersystem crossing intramolecular involved k₁ kcal/mole ketones lifetime magnetic field mechanism molecular molecule naphthalene nuclear geometry observed occur organic molecules oscillator overlap oxetane oxygen pathway phosphorescence photochemical photochemistry photocycloaddition photon photoreactions photosensitized Phys possess processes quantum yield quencher quenching radiationless transitions radiative radical pair rate constant reactant reaction reactive rearrangement representative point result S₁ S₁ and T₁ sensitizer singlet solvent spectroscopic spectrum spin-orbit coupling structure surface symmetry T₁ T₂ temperature triplet triplet-triplet Turro undergo vector vibrational Zero Order zwitterionic