The Chemistry of Peroxides, Parts 1 and 2John Wiley & Sons, 6 de fev. de 2007 - 1536 páginas The Chemistry of Peroxides is a new volume in the Chemistry of Functional Groups series. This series covers all aspects of organic chemistry with each volume containing chapters on:
Edited by Zvi Rappoport, this series provides outstanding reviews on all aspects of functional groups in analytical, physical, synthetic and applied chemistry. |
Conteúdo
| 1 | |
2 The structural chemistry of acyclic organic peroxides | 93 |
3 Thermochemistry of peroxides | 145 |
4 17O NMR spectroscopy of organic compounds containing the OO group | 171 |
5 Synthesis of cyclic peroxides | 189 |
6 Synthetic uses of peroxides | 307 |
7 Analytical and safety aspects of organic peroxides and related functional groups | 597 |
8 Silicon and germanium peroxides | 775 |
11 Peroxides in biological systems | 915 |
12 Sulfur and phosphorus peroxides | 1001 |
13 Transition metal peroxides Synthesis and role in oxidation reactions | 1053 |
14 Contemporary dioxirane chemistry Epoxidations heteroatom oxidations and CH insertions | 1129 |
15 Contemporary trends in dioxetane chemistry | 1171 |
16 Chemiluminescence of organic peroxides | 1211 |
17 Biomimetic FeII chemistry and synthetic studies on antimalarial and antitumour endoperoxides | 1279 |
| 1347 | |
9 Selective formation of allylic hydroperoxides via singlet oxygen ene reaction | 831 |
10 Polar effects in decomposition of peroxidic compounds and related reactions | 899 |
Termos e frases comuns
17O NMR activation barrier adduct aldehydes alkenes alkyl alkyl hydroperoxides allylic alcohols anion aqueous asymmetric atom calculated carbonyl catalyst Chem chemical chemistry chiral complex compounds corresponding coworkers cyclic peroxides decomposition derivatives determination dialkyl peroxides diastereomers diastereoselectivity dioxirane double bond electron enantiomeric enantiomeric excess enantioselectivity endoperoxides enthalpy of formation epoxidation equation ester ether ethylene free radical HO−ONO hydrogen peroxide hydroperoxides hydroxyl interactions intermediate kcal kcal mol−1 ketones kinetic kJ mol−1 ligand lipid MeOH method methyl molecular molecules nucleophilic O−O bond obtained OH OH olefins organic organic peroxides oxidation ozone ozonides ozonolysis peracid peroxynitrous acid Ph Ph photooxygenation Phys presence reaction reactive regioselectivity Scheme selectivity singlet oxygen solution solvent species stability steric substituents substrates sulfides sulfoxide synthesis t-Bu Table TBHP temperature tert-butyl Tetrahedron Lett trans transition structures yield